Preparation of Ca/Al-Layered Double Hydroxides/Biochar Composite with High Adsorption Capacity and Selectivity toward Cationic Dyes in Aqueous

Risfidian Mohadi; Neza Rahayu Palapa; Aldes Lesbani

doi:10.9767/bcrec.16.2.10211.244-252

DOI: https://doi.org/10.9767/bcrec.16.2.10211.244-252

Preparation of Ca/Al-Layered Double Hydroxides/Biochar Composite with High Adsorption Capacity and Selectivity toward Cationic Dyes in Aqueous

Risfidian Mohadi^{1, 2}

, Neza Rahayu Palapa³

, Aldes Lesbani^{4, 2}

¹Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, South Sumatera, Indonesia

²Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, South Sumatera, Indonesia

³Graduate School, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, South Sumatera, Indonesia

⁴ Graduate School, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, South Sumatera, Indonesia , Indonesia

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Received: 28 Jan 2021; Revised: 6 Apr 2021; Accepted: 9 Apr 2021; Available online: 12 Apr 2021; Published: 30 Jun 2021.

Editor(s): Bunjerd Jongsomjit

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.

BibTex Citation Data :

@article{BCREC10211,
    author = {Risfidian Mohadi and Neza Palapa and Aldes Lesbani},
    title = {Preparation of Ca/Al-Layered Double Hydroxides/Biochar Composite with High Adsorption Capacity and Selectivity toward Cationic Dyes in Aqueous},
    journal = {Bulletin of Chemical Reaction Engineering & Catalysis},
  volume = {16},
    number = {2},
    year = {2021},
    keywords = {Selectivity; Cationic Dyes; Ca/Al-LDH; Biochar; Composite Materials},
    abstract = { Widely reports have evaluated the use of biochar (BC) composites to layered double hydroxide (LDH) to adsorb dyes from wastewater. However, its applicability for adsorbing a mixture of cationic dyes such as Malachite green (MG), Rodhamine-B (Rh-B), and Methylene blue (MB), which causes carcinogenic and mutagenic effects on aquatic life, has not been studied. In this work, we compared the performance of CaAl-LDH/BC adsorbent with or without the addition of BC in the adsorption of cationic dyes. The adsorption study was prepared in a batch system using various temperatures, concentrations, and also contact time. The results of the characterization of Ca/Al-Biochar composite showed the unique diffraction of XRD pattern, and also showed two characteristics of starting materials. Surface area analysis by BET method showed Ca/Al-Biochar composite has a higher surface area than starting material. The results of the adsorption study of MG showed that Ca/Al-Biochar follows the pseudo-second-order kinetic model. The adsorption capacity of MG on Ca/Al-Biochar was up to 71.429 mg/g and shows selectivity toward MG in an aqueous solution. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License ( https://creativecommons.org/licenses/by-sa/4.0 ).    },
   issn = {1978-2993},   pages = {244--252}  doi = {10.9767/bcrec.16.2.10211.244-252},
    url = {https://ejournal2.undip.ac.id/index.php/bcrec/article/view/10211}
}

Citation Format:

Abstract

Widely reports have evaluated the use of biochar (BC) composites to layered double hydroxide (LDH) to adsorb dyes from wastewater. However, its applicability for adsorbing a mixture of cationic dyes such as Malachite green (MG), Rodhamine-B (Rh-B), and Methylene blue (MB), which causes carcinogenic and mutagenic effects on aquatic life, has not been studied. In this work, we compared the performance of CaAl-LDH/BC adsorbent with or without the addition of BC in the adsorption of cationic dyes. The adsorption study was prepared in a batch system using various temperatures, concentrations, and also contact time. The results of the characterization of Ca/Al-Biochar composite showed the unique diffraction of XRD pattern, and also showed two characteristics of starting materials. Surface area analysis by BET method showed Ca/Al-Biochar composite has a higher surface area than starting material. The results of the adsorption study of MG showed that Ca/Al-Biochar follows the pseudo-second-order kinetic model. The adsorption capacity of MG on Ca/Al-Biochar was up to 71.429 mg/g and shows selectivity toward MG in an aqueous solution. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

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Keywords: Selectivity; Cationic Dyes; Ca/Al-LDH; Biochar; Composite Materials

Funding: Universitas Sriwijaya under contract 0687/UN9/SK.BUK.KP/20

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Section: Original Research Articles

Language : EN

In 2021: BCREC Volume 16 Issue 2 Year 2021 (June 2021)

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