Preparation, Characterization, and Catalytic Property of a Cu(II) Complex with 2-Carboxybenzaldehyde-p-Toluenesulfonyl Hydrazone Ligand

DOI: https://doi.org/10.9767/bcrec.13.1.1012.7-13
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Submitted: 16-03-2017
Published: 02-04-2018
Section: Original Research Articles
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Metal-organic complex hybrid materials constructed from carboxylate ligands and hydrazone ligands have exhibited potential application in many fields. In order to enrich the applications of the metai-organic complex materials, a new hydrazone ligand contains carboxylate group, 2-carboxybenzaldehyde-p-toluenesulfonyl hydrazone (L1), and its Cu(II) complex (C2), have been prepared. The structure of L1 was determined by elemental analysis, IR spectra and single crystal X-ray diffraction, and the composition of Cu(II) complex (C2) has also been determined by elemental analysis, IR and UV spectra. The catalytic activity for A3 coupling reaction of benzaldehyde, piperidine, and phenylacetylene has been investigated. The results show that Cu(II) complex displays a 100 % selectivity to the product of propargylamine during A3 coupling reaction and benzaldehyde conversions were 95.3, 94.2, and 93.4 % at 120 °C for 12 h in the first, second, and third reaction cycles, respectively.  Copyright © 2018 BCREC Group. All rights reserved

Received: 16th March 2017; Revised: 17th July 2017; Accepted: 18th July 2017; Available online: 22nd January 2018; Published regularly: 2nd April 2018

How to Cite: Tai, X.S., Li, P.F., Liu, L.L. (2018). Preparation, Characterization, and Catalytic Property of a Cu(II) Complex with 2-Carboxybenzaldehyde-p-Toluenesulfonyl Hydrazone Ligand. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1): 7-13 (doi:10.9767/bcrec.13.1.1012.7-13)

 

Keywords

Hydrazone ligand; Cu(II) complex material; Catalyst preparation and characterization; Catalytic property

  1. Xi Shi Tai 
    College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China
  2. Peng Fei Li 
    College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266061, China
  3. Li Li Liu 
    College of Chemistry and Chemical Engineering, Weifang University, Weifang 261061, China
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