Effects of Weight Hourly Space Velocity and Catalyst Diameter on Performance of Hybrid Catalytic-Plasma Reactor for Biodiesel Synthesis over Sulphated Zinc Oxide Acid Catalyst

DOI: https://doi.org/10.9767/bcrec.12.2.775.227-234
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Submitted: 15-11-2016
Published: 01-08-2017
Section: The 2nd International Seminar on Chemistry (ISoC 2016) (Surabaya, 26-27 July 2016)

Biodiesel synthesis through transesterification of soybean oil with methanol on hybrid catalytic-plasma reactor over sulphated zinc oxide (SO42-/ZnO) active acid catalyst was investigated. This research was aimed to study effects of Weight Hourly Space Velocity (WHSV) and the catalyst diameter on performance of the hybrid catalytic-plasma reactor for biodiesel synthesis. The amount (20.2 g) of active sulphated zinc oxide solid acid catalysts was loaded into discharge zone of the reactor. The WHSV and the catalyst diameter were varied between 0.89 to 1.55 min-1 and 3, 5, and 7 mm, respectively. The molar ratio of methanol to oil as reactants of 15:1 is fed to the reactor, while operating condition of the reactor was kept at reaction temperature of 65 oC and ambient pressure. The fatty acid methyl ester (FAME) component in biodiesel product was identified by Gas Chromatography - Mass Spectrometry (GC-MS). The results showed that the FAME yield decreases with increasing WHSV. It was found that the optimum FAME yield was achieved of 56.91 % at WHSV of 0.89 min-1 and catalyst diameter of 5 mm and reaction time of 1.25 min. It can be concluded that the biodiesel synthesis using the hybrid catalytic-plasma reactor system exhibited promising the FAME yield. Copyright © 2017 BCREC Group. All rights reserved

Received: 15th November 2016; Revised: 24th December 2016; Accepted: 16th February 2017

How to Cite: Buchori, L., Istadi, I., Purwanto, P. (2017). Effects of Weight Hourly Space Velocity and Catalyst Diameter on Performance of Hybrid Catalytic-Plasma Reactor for Biodiesel Synthesis over Sulphated Zinc Oxide Acid Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2): 227-234 (doi:10.9767/bcrec.12.2.775.227-234)

Permalink/DOI: http://dx.doi.org/10.9767/bcrec.12.2.775.227-234

 

Keywords

Biodiesel; Sulphated zinc oxide; Hybrid catalytic-plasma reactor; Transesterification

  1. Luqman Buchori  Scholar
    Department of Chemical Engineering, Faculty of Engineering, Diponegoro University Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275, , Indonesia
    (Scopus ID = 55559743300), Department of Chemical Engineering, Diponegoro University
  2. Istadi Istadi 
    Department of Chemical Engineering, Faculty of Engineering, Diponegoro University Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275, , Indonesia
  3. Purwanto Purwanto 
    Department of Chemical Engineering, Faculty of Engineering, Diponegoro University Jl. Prof. Soedarto, SH, Kampus Undip Tembalang, Semarang 50275 , Indonesia

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