Green Synthesis of Gold Nanoparticles using Aqueous Garlic (Allium sativum L.) Extract, and Its Interaction Study with Melamine
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Gold nanoparticles (AuNPs) have been successfully prepared by green synthesis method using aqueous extract of garlic with the Latin name of Allium sativum L. (ASL) as a reducing and stabilizing agents. Identification of active compounds in aqueous ASL extract was conducted by phytochemical analysis and Fourier transform infrared (FTIR) spectroscopy, while the synthesized AuNPs were characterized using UV-Vis spectrophotometer and transmission electron microscopy-selected area electron diffraction (TEM-SAED). The AuNPs formation was optimized at aqueous ASL extract concentration of 0.05%, HAuCl4 concentration of 2.0×10-4 M, and pH of 3.6. The optimized AuNPs was characterized using TEM, and has a spherical shape with particle size of 15±3 nm. The particles were also stable up until one month. The synthesized AuNPs has been studied its interaction with melamine, and showed the optimum pH of interaction at 3.6. Copyright © 2017 BCREC GROUP. All rights reserved
Received: 13rd November 2016; Revised: 3rd January 2017; Accepted: 10th February 2017
How to Cite: Yulizar, Y., Ariyanta, H.A., Abdurrachman, L. (2017). Green Synthesis of Gold Nanoparticles using Aqueous Garlic (Allium sativum L.) Extract, and Its Interaction Study with Melamine. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2): 212-218 (doi:10.9767/bcrec.12.2.770.212-218)
Ahmed, S., Ahmad, M., Swami, B.L., Ikram, S. (2016). A review on plants extract mediated synthesis of silver nanoparticles for antimicrobial applications: A green expertise. Journal of Advanced Research, 7: 17-28. doi:10.1016/j.jare.2015.02.007.
Almeida, C.L.F.D., Falcao, H.D.S., Lima, G.R.D.M., Montenegro, C.D.A., Lira, N.S., Athayde-Filho, P.F.D., Rodrigues, L.C., Souza, M.D.F.V., Barbosa-Filho, J.M., Batista, L.M. (2011). Bioactivities from Marine Algae of the Genus Gracilaria. International Journal of Molecular Sciences, 12: 4550-4573.
Vadlapudi, V. (2014). Green Synthesis of Silver and Gold Nanoparticles. Middle-East Journal of Scientific Research, 19: 834-842.
Kirtee, W., Choudhari, A., Chikate, R., Kaul-Ghanekar, R. (2013). Synthesis and Characterization of Gold Nanoparticles Using Ficus Religiosa Extract. Carbon - Science and Technology, 5: 203-210.
Arunachalam, K.D., Annamalai, S.K,. Hari, S. (2013). One-step Green Synthesis and Characterization of Leaf Extract-Mediated Biocompatible Silver and Gold Nanoparticles from Memecylon umbellatum. International Journal of Nanomedicine, 8: 1307-1315
Aromal, S.A., Vidhu, V.K., Philip, D. (2012). Green Synthesis of Well-Dispersed Gold Nanoparticles using Macrotyloma uniflorum. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 85: 99-104
Kalishwaralal, K., Deepak, V., Pandian, S.B.R.K., Kottaisamy, M., Barathmani Kanth, S., Kartikeyan, B., Gurunathan, S. (2010). Biosynthesis of Silver and Gold Nanoparticles using Brevibacterium casei. Colloids and Surfaces B: Biointerfaces, 77: 257-262.
Philip, D. (2009). Honey Mediated Green Synthesis of Gold Nanoparticles. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 73: 650-653
Sujitha, M.V., Kannan, S. (2013). Green Synthesis of Gold Nanoparticles using Citrus Fruits (Citrus Limon, Citrus Reticulata and Citrus Sinensis) Aqueous Extract and Its Characterization. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 102: 15-23.
Tamuly, C., Hazarika, M., Borah, S.C., Das, M.R., Boruah, M.P. (2013). In situ Biosynthesis of Ag, Au and Bimetallic Nanoparticles using Piper pedicellatum. DC: Green chemistry approach. Colloids and Surfaces B: Biointerfaces, 102: 627-634
Kumar, K.M., Mandal, B.K., Sinha, M., Krishnakumar, V. (2012). Terminalia chebula Mediated Green and Rapid Synthesis of Gold Nanoparticles. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 86: 490-494.
Das, R.K., Gogoi, N., Bora, U. (2011). Green Synthesis of Gold Nanoparticles using Nyctanthes arbortristis Flower Extract. Bioprocess and Biosystems Engineering, 34: 615-619
Philip, D., Unni, C., Aromal, S.A., Vidhu, V.K. (2011). Murraya Koenigii Leaf-Assisted Rapid Green Synthesis of Silver and Gold Nanoparticles. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 78: 899-904.
Philip, D. (2010). Rapid Green Synthesis of Spherical Gold Nanoparticles using Ma-ngifera indica Leaf. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,77: 807-810
Smitha, S.L., Philip, D., Gopchandran, K.G. (2009). Green Synthesis of Gold Nanoparticles using Cinnamomum zeylanicum Leaf Broth. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 74: 735-739.
Vinod, V.T.P., Saravanan, P., Sreedhar, B.D., Devi, D.K., Sashidhar, R.B. (2011). Colloids and Surfaces B: Biointerfaces, 83: 291-298.
Kumar, K.P., Paul, W., Sharma, C.P. (2011). Green Synthesis of Gold Nanoparticles with Zingiber officinale Extract: Characterization and Blood Compatibility. Process Biochemistry, 46: 2007-2013.
Gavade, N.L., Kadam, A.N., Suwarnkar, M.B., Ghodake, V.P., Garadkar, K.M. (2015). Biogenic Synthesis of Multi-Applicative Silver Nanoparticles by using Ziziphus Jujuba Leaf Extract. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,136: 953-960
Song, J.Y., Jang, H.K., Kim, B.S. (2009). Biological Synthesis of Gold Nanoparticles using Magnolia Kobus and Diopyros Kaki Leaf Extracts. Process Biochem., 44: 1133-1138
Ariyanta, H.A., Yulizar, Y. (2016). The Shape Conversion of Silver Nanoparticles through Heating and Its Application as Homogeneous Catalyst in Reduction of 4-Nitrophenol. IOP Conf. Series: Materials Science and Engineering, 107: 012002
Yulizar, Y., Foliatini., Hafizah, M.A.E. (2016). A Facile and Effective Technique for the Synthesis of Thiol-Modified Au/Alginate Nanocomposite and Its Performance in Stabilizing Pickering Emulsion. Arabian Journal of Chemistry (In Press), http://dx.doi.org/ 10.1016/j.arabjc.2016.05.013
Foliatini., Yulizar, Y., Hafizah, M.A.E. (2015). The Synthesis of Alginate-Capped Silver Nanoparticles under Microwave Irradiation. Journal of Mathematical and Fundamental Sciences, 47: 31-50
Tomar, A., Garg, G. (2013). Short Review on Application of Gold Nanoparticles. Global Journal of Pharmacology, 7: 34-38
Vadlapudi, V., Kaladhar, D. (2014). Review: Green Synthesis of Silver and Gold Nanoparticles. Middle-East Journal of Scientific Research,19: 834-842
Ahamed, M., Khan, M.A.M., Siddiqui, M.K.J., AlSalhi, M.S., Alrokayan, S.A. (2011). Green Synthesis, Characterization and Evaluation of Biocompatibility of Silver Nanoparticles. Physica E, 43: 1266-1271
Song, J., Wu, F., Wan, Y., Ma, L. (2015). Co-lorimetric Detection of Melamine in Pretreated Milk using Silver Nanoparticles Functionalized with Sulfanilic Acid. Food Control, 50: 356-361
Xin, J.Y., Zhang, L.X., Chen, D.D., Lin, K., Fan, H.C., Wang, Y., Xia, C.G. (2015). Colorimetric Detection of Melamine Based on Methanobactin-Mediated Synthesis of Gold Nanoparticles. Food Chemisry,174: 473-479
Du, J., Wang, Y., Zhang, W. (2015). Gold Nanoparticles-based Chemiluminescence Resonance Energy Transfer for Ultrasensitive Detection of Melamine. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,149: 698-702
Kumar, N., Seth, R., Kumar, H. (2014). Colorimetric Detection of Melamine in Milk by Ci-trate-Stabilized Gold Nanoparticles. Analytical Biochemistry, 456: 43-49
Mbaveng, A.T., Hamm, R., Kuete, V. 1st eds. (2014). Toxicological Survey of African Medical Plants. Reading, Mass.: Elsevier.
Rastogi, L., Arunachalam, J. (2011). Sunlight based Irradiation Strategy for Rapid Green Synthesis of Highly Stable Silver Nanoparticles using Aqueous Garlic (Allium sativum) Extract and their Antibacterial Potential. Materials Chemistry and Physics,129: 558-563
Stan, M., Popaa, M., Toloman, M., Dehelean, A., Lung, I., Katona, G. (2015). Enhanced Photocatalytic Degradation Properties of Zinc Oxide Nanoparticles Synthesized by using Plant Extracts. Materials Science in Semiconductor Processing, 39: 23-29
Philip, D., Unni, C. (2011). Extracellular Biosynthesis of Gold and Silver Nanoparticles using Krishna tulsi (Ocimum sanctum) Leaf. Physica E, 43: 1318-1322.
Yallappa, S., Manjanna, J., Dhananjaya, B.L. (2015). Phytosynthesis of Stable Au, Ag and Au-Ag Alloy Nanoparticles using J. Sambac Leaves Extract, and Their Enhanced Antimicrobial Activity in Presence of Organic Antimicrobials. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 137: 236-243
Devi, P.R., Kumar, C.S., Selvamani, P., Subramanian, N., Ruckmani, K. (2015). Synthesis and Characterization of Arabic Gum Capped Gold Nanoparticles for Tumor-Targeted Drug Delivery. Materials Letters,139: 241-244
Philip, D. (2010). Honey Mediated Green Synthesis of Silver Nanoparticles. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 75: 1078-1081.
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